Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 358, Issue 10, Pages 1671-1678Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201600084
Keywords
aldehydes; diazo compounds; organocatalysis; photocatalysis; radicals
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Funding
- Ministry of Science and Higher Education [N NT204 187139]
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Photocatalytic reactions of diazoacetates with aldehydes led to alpha-alkylated carbonyl compounds instead of the expected cyclopropane derivatives. The reaction requires a dual catalytic system photocatalysis merged with enamine-iminium catalysis. NMR, EPR, UV/Vis, and ESI-MS analyses provided sufficient data to corroborate the proposed radical mechanism-enamine catalysis merged with photocatalysis.
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