Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 358, Issue 6, Pages 880-886Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201500709
Keywords
carbocyclization; C-H activation; alpha-diazo esters; iridium(III) and rhodium(III) catalysis; 2-phenylimidazo[1,2-a]pyridines
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Funding
- Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- NSFC [21472186, 21272231]
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Iridium(III) and rhodium(III) complexes can catalyze the carbocyclization between 2-phenylimidazo[1,2-a]pyridine and alpha-diazo esters. The reaction occurs via C-H activation and dialkylation of the arene followed by intramolecular nucleophilic substitution. Iridium(III) and rhodium(III) catalysis offer complementary scopes with respect to the alpha-diazo esters.
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