Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 358, Issue 14, Pages 2324-2331Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201600382
Keywords
cyclization; lactams; lactones; pincer complexes; platinum
Categories
Funding
- Centre National de la Recherche Scientifique
- Universite de Toulouse
- Agence Nationale de la Recherche (ANR) [CE6-CYCLOOP]
- Consejo Nacional de Cienca y tecnologia (CONACYT)
- Chinese Scholarship Council (CSC)
Ask authors/readers for more resources
Platinum pincer complexes featuring an SCS indenediide backbone have been prepared and evaluated in the catalytic cycloisomerization of alkynoic acids and N-tosyl alkynylamides. One of the platinum complexes significantly outperforms its palladium analogue for the formation of 6- and 7-membered rings. The catalytic system takes advantage of the alkynophilicity of Pt and of the non-innocent character of the indenediide framework. Like for Pd, the catalytic performance is significantly improved by using an H-bond donor additive such as pyrogallol. For the first time, a large variety of omega-unsaturated delta- and epsilon-lactones/lactams could be prepared with high selectivities and in very good yields.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available