Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 358, Issue 15, Pages 2431-2435Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201600378
Keywords
aryl halides; benzyl halides; cobalt; cross-coupling; diarylmethanes
Categories
Funding
- Ecole polytechnique
- CNRS
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A new protocol for the direct reductive cobalt-catalyzed arylation of benzyl chlorides has been developed in order to form functionalized diarylmethanes. A variety of reactive groups either on the aryl or the benzyl halide was employed. This represents the first cobalt-catalyzed reductive cross-coupling which does not require any ligand and pyridine. A reaction pathway is proposed involving a radical benzyl species.
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