Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 358, Issue 15, Pages 2410-2416Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201600590
Keywords
arylsilanes; carbamates; C-O activation; copper(II) fluoride (CuF2); Hiyama reaction
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Funding
- 973 Project by the MOST of China [2015CB856600]
- NSFC [21332001]
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Aryl carbamates were for the first time applied as electrophiles in the cross-coupling with arylsilanes via nickel or iron catalysis to construct valuable biaryl compounds. This new coupling reaction features a good group tolerance and non-sensitivity to steric hindrance on both aryl carbamates and arylsilanes.
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