Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 358, Issue 9, Pages 1526-1533Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201600158
Keywords
alcohols; alkynes; diazo compounds; gold; photocatalysis
Categories
Funding
- MINECO
- FEDER [CTQ2012-33664-C02-01, CTQ2012-33664-C02-02, CTQ2015-65060-C2-1-P, CTQ2015-65060-C2-2-P]
Ask authors/readers for more resources
A method for the arylative coupling of alkynols or alkynyl hydroperoxides using equimolar amounts of diazonium salts at room temperature has been achieved through application of a gold/photoredox dual catalytic system. The excess of external reagents (oxidant or base) and high temperatures required by previous arylative Meyer-Schuster rearrangement protocols are avoided by exploitation of a visible light-mediated process.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available