Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 358, Issue 20, Pages 3313-3318Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201600804
Keywords
Au/TiO2; hydroamination; indoles; recyclable; supported gold nanoparticles
Categories
Funding
- National Science Foundation [CHE-1401700]
- National Science Foundation of China [NSFC-21472018]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1401700] Funding Source: National Science Foundation
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Commercial gold nanoparticles supported on titanium dioxide (TiO2) were found to be a highly efficient catalyst for alkyne hydroamination. Terminal alkynes could easily undergo intermolecular hydroamination with low catalyst loadings (0.2 mol% Au) under solvent-free conditions. Indoles were efficiently synthesized using microwave heating through intramolecular hydroamination.
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