Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 358, Issue 15, Pages 2460-2468Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201501179
Keywords
homogeneous catalysis; iron; phosphines; porphyrins; Schiff bases
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Funding
- University of Bath
- EPSRC [EP/M019810/1]
- EPSRC [EP/M019810/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/M019810/1] Funding Source: researchfish
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The importance of phosphines in synthetic chemistry cannot be underestimated. Catalytic hydrophosphination offers an ideal method to prepare P-C bonds without the need for harsh reaction conditions or stoichiometric amounts of waste by-product. We herein report our studies into two biocompatible iron(III) complexes in hydrophosphination chemistry using diphenylphosphine under mild and benign reaction conditions (room temperature, sol-vent-free) and our extended exploration of hydrophosphination with phenylphosphine, which can be tuned to operate in the absence of catalyst under thermal conditions for single hydrophosphination or solvent-free with an iron(III) precatalyst to generate the products of double hydrophosphination.
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