4.8 Article

Directed Growth of Metal-Organic Frameworks and Their Derived Carbon-Based Network for Efficient Electrocatalytic Oxygen Reduction

Journal

ADVANCED MATERIALS
Volume 28, Issue 12, Pages 2337-2344

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201505086

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Funding

  1. National Natural Science Foundation of China (NSFC)
  2. 973 Program [2014CB932102]
  3. China National Funds for Distinguished Young Scientists of the NSFC

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A honeycomb-like carbon-based network is obtained by in situ nucleation and directed growth of metal-organic framework (MOF) arrays on the surface of layered double hydroxide (LDH) nano platelets, followed by a subsequent pyrolysis process, which exhibits largely enhanced electrocatalytic ORR performances. A successful paradigm for the directed growth of highly oriented MOF arrays is demonstrated, with potential applications for energy storage and conversion.

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