4.8 Article

Giant Enhancement of Internal Electric Field Boosting Bulk Charge Separation for Photocatalysis

Journal

ADVANCED MATERIALS
Volume 28, Issue 21, Pages 4059-4064

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201600301

Keywords

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Funding

  1. National Natural Science Funds for Distinguished Young Scholars [21425728]
  2. National Basic Research Program of China (973 Program) [2013CB632402]
  3. National Natural Science Foundation of China [21377044, 51472100, 21573085]
  4. Excellent Doctorial Dissertation Cultivation Grant from Central China Normal University [2015YBZD019]

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Incorporating carbon into Bi3O4 Cl enhances its internal electric field by 126 times, which induces a bulk charge separation efficiency (eta(bulk)) of 80%. This ultrahigh eta(bulk) value presents a state-of-the-art result in tuning the bulk charge separation. The generated C-doped Bi3O4Cl has a noble-metal-and electron-scavenger-free water-oxidation ability under visible light, which is difficult to achieve with most existing photocatalysts.

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