4.8 Article

Submonolayered Ru Deposited on Ultrathin Pd Nanosheets used for Enhanced Catalytic Applications

Journal

ADVANCED MATERIALS
Volume 28, Issue 46, Pages 10282-10286

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201604829

Keywords

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Funding

  1. MOE [ARC 26/13, MOE2013-T2-1-034, ARC 19/15, MOE2014-T2-2-093, MOE2015-T2-2-057, RG5/13]
  2. NTU under Start-Up Grant in Singapore [M4081296.070.500000]
  3. National Program on Key Basic Research Project [2014CB921002]
  4. Strategic Priority Research Program of Chinese Academy of Sciences [XDB07030200]
  5. National Natural Science Foundation of China [51522212, 51421002, GZ213054, 51322202]
  6. Joint Research Fund for Overseas Chinese, Hong Kong and Macao Scholars [51528201]
  7. Natural Science Foundation of Jiangsu Province in China [BK20130927]

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Ultrathin Pd nanosheets (NSs) coated with submonolayered Ru, referred to as Pd@Ru NSs, are synthesized via a seed-mediated growth method. The underpotential deposition can be the driving force for the formation of Pd@Ru NSs. The Pd@Ru NSs exhibit superior catalytic properties in the reduction of 4-nitrophenol and the semihydrogenation of 1-octyne, compared to the pure Pd NSs and Ru NSs.

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