Journal
ADVANCED MATERIALS
Volume 28, Issue 45, Pages 9969-9977Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201603112
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Funding
- Basic Research Fund of Shenzhen City [JCYJ20140714151402769, JCYJ20150630145302236]
- Shenzhen Peacock Plan project [KQTD20140630110339343]
- National Science Foundation of China (NSFC) [51573076]
- Shenzhen Key Lab [ZDSYS201505291525382]
- Guangdong Natural Science Foundation [2015A030313900]
- South University of Science and Technology of China [FRG-SUSTC1501A-72]
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Narrow bandgap (1.37-1.46 eV) polymers incorporating a head-to-head linkage containing 3-alkoxy-3'-alkyl-2,2'-bithiophene are synthesized. The head-to-head linkage enables polymers with sufficient solubility and the noncovalent sulfur-oxygen interaction affords polymers with high degree of backbone planarity and film ordering. When integrated into polymer solar cells, the polymers show a promising power conversion efficiency approaching 10%.
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