4.8 Article

Entrapment of Polysulfides by a Black-Phosphorus-Modified Separator for Lithium-Sulfur Batteries

Journal

ADVANCED MATERIALS
Volume 28, Issue 44, Pages 9797-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201602172

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Funding

  1. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [DE-AC02-76SF00515]

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A bifunctional separator modified by black-phosphorus nanoflakes is prepared to overcome the challenges associated with the polysulfide diffusion in lithium-sulfur batteries. It brings the benefits of the entrapment of various sulfur species via the strong binding energy and reactivation of the trapped sulfur species due to its high electron conductivity as well as Li-ion diffusivity.

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