4.8 Article

Reactive Multifunctional Template-Induced Preparation of Fe-N-Doped Mesoporous Carbon Microspheres Towards Highly Efficient Electrocatalysts for Oxygen Reduction

Journal

ADVANCED MATERIALS
Volume 28, Issue 36, Pages 7948-7955

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201602490

Keywords

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Funding

  1. 100 Talents Programme of the Chinese Academy of Sciences
  2. National Program on Key Basic Research Project of China (973 Program) [2012CB215500]
  3. Foundation for Innovative Research Groups of the National Natural Science Foundation of China [20921002]
  4. National Natural Science Foundation of China [21101147]
  5. Jilin Province Science and Technology Development Program [20100102, 20116008]

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A novel in situ replication and polymerization strategy is developed for the synthesis of Fe-N-doped mesoporous carbon microspheres (Fe-NMCSs). This material benefits from the synergy between the high catalytic activity of Fe-N-C and the fast mass transport of the mesoporous microsphere structure. Compared to commercial Pt/C catalysts, the Fe-NMCSs show a much better electrocatalytic performance in terms of higher catalytic activity, selectivity, and durability for the oxygen reduction reaction.

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