Journal
ADVANCED MATERIALS
Volume 28, Issue 48, Pages 10772-+Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201603381
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Funding
- NSFC [21473129, 91422302, 21620102002]
- National 1000 Young Talents program
- US NSF [CHE-1152609]
- Wuhan National High Magnetic Field Center [2015KF06]
- Fundamental Research Funds for the Central University
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A lanthanide cluster, PCC-72, which is the second largest, with 72 Dy(III) ions assembled into an unprecedented tubular structure, is synthesized. Remarkably, PCC-72 exhibits superionic proton conductivity (>10(-4) S cm(-1)) under both ambient (with relative humidity RH < 75%) and hot (T > 90 degrees C, RH = 95%) conditions. Moreover, slow magnetic relaxation is observed, making PCC-72 the largest Dy(III) cluster that is a single-molecule magnet.
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