4.8 Article

A Perovskite Electrocatalyst for Efficient Hydrogen Evolution Reaction

Journal

ADVANCED MATERIALS
Volume 28, Issue 30, Pages 6442-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201600005

Keywords

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Funding

  1. Key Projects in Nature Science Foundation of Jiangsu Province [BK2011030]
  2. National Nature Science Foundation of China [21576135]
  3. Educational Commission of Jiangsu Province of China [13KJA430004]
  4. Priority Academic Program Development of Jiangsu Higher Education Institutions
  5. Program for Jiangsu Specially-Appointed Professors
  6. Youth Fund in Jiangsu Province [BK20150945]

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Perovskite oxides are demonstrated for the first time as efficient electrocatalysts for the hydrogen evolution reaction (HER) in alkaline solutions. A-site praseodymium-doped Pr-0.5(Ba0.5Sr0.5)(0.5)Co0.8Fe0.2O3-delta (Pr0.5BSCF) exhibits dramatically enhanced HER activity and stability compared to Ba0.5Sr0.5Co0.8Fe0.2O3-delta (BSCF), superior to many well-developed bulk/nanosized nonprecious electrocatalysts. The improved HER performance originates from the modified surface electronic structures and properties of Pr0.5BSCF induced by the Pr-doping.

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