Propeller-Like Nanorod-Upconversion Nanoparticle Assemblies with Intense Chiroptical Activity and Luminescence Enhancement in Aqueous Phase

Propeller-like nanoscale assemblies with exceptionally intense chiroptical activity and strong luminescence are prepared using gold nanorods and upconversion nano particles. The circular dichroism intensity of the tetramer reached 80.9 mdeg, with g-factor value of 2.1 x 10(-2). The enhancement factor of upconversion luminescence is as high as 21.3 in aqueous phase. Attomolar bioanalysis of a cancer biomarker with two model is also achieved, showing potential for early disease diagnosis and environmental monitoring.