4.8 Article

Metal-Organic Framework Templated Synthesis of Copper Azide as the Primary Explosive with Low Electrostatic Sensitivity and Excellent Initiation Ability

Journal

ADVANCED MATERIALS
Volume 28, Issue 28, Pages 5837-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201601371

Keywords

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Funding

  1. State Key Laboratory of Explosion Science and Technology [YB2016-16]
  2. Science and Technology on Applied Physical Chemistry Laboratory [9140C370303120C37142]
  3. 973 Program [2013CB834704]
  4. Provincial Key Project of China [7131253]
  5. National Natural Science Foundation of China [21471018, 21404010, 21201018, 21490574]
  6. 1000 Plan (Youth)

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A powerful yet safe primary explosive, embedded in a conductive carbon scaffold, is prepared by using a metal-organic framework as precursor. It simultaneously possesses low electrostatic sensitivity, good flame sensitivity, and excellent initiation ability. This method is simple, scalable, and provides a new platform for the development of energetic materials especially those employed in miniaturized explosive systems.

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