4.8 Article

Controlling Molecular Ordering in Aqueous Conducting Polymers Using Ionic Liquids

Journal

ADVANCED MATERIALS
Volume 28, Issue 39, Pages 8625-8631

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201505473

Keywords

-

Funding

  1. National Research Foundation of Korea (NRF) - Korea government (MSIP) [NRF-2014R1A2A1A09006137, NRF-2015K1A3A1A16002247]
  2. Global PHD Fellowship Program through the NRF - Ministry of Education [2014H1A2A1022257]
  3. R&D program of MSIP/Commercializations Promotion Agency for RD Outcomes [2015K000199]
  4. Technology Development Program to Solve Climate Changes of the NRF - Ministry of Science, Information and Communication Technology and Future Planning [NRF-2015M1A2A2057510]
  5. Core Technology Development Program for Next -generation Solar Cells Project - GIST
  6. Basic Research Program of the NRF [2013R1A1A3012254]
  7. Grand Challenge [KSC-2015-C3-014]
  8. Partnership and Leadership for the nationwide Supercomputing Infrastructure supercomputing resources of Korea Institute of Science and Technology Information
  9. MSIP
  10. POSTECH
  11. Ministry of Science, ICT & Future Planning, Republic of Korea [GIST-14] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
  12. National Research Foundation of Korea [2015M1A2A2057510, 2013R1A1A3012254, 2014H1A2A1022257, 2014R1A2A1A09006137] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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The molecular ordering of aqueous conducting polymers is controlled using a rational method. By introducing various ionic liquids, which have designed electrostatic interactions to PEDOT:PSS solutions, the evolution of the molecular ordering of the PEDOT is manipulated. Consequently, highly ordered nano structures are achieved with a reduced pi-pi stacking distance of approximate to 3.38 angstrom and, thus, a maximum sigma(dc) of approximate to 2100 S cm(-1)

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