4.8 Article

Two Birds with One Stone: Tailoring Singlet Fission for Both Triplet Yield and Exciton Diffusion Length

Journal

ADVANCED MATERIALS
Volume 28, Issue 34, Pages 7539-7547

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201600968

Keywords

exciton transport; Frenkel excitons; pump-probe microscopy; triplet fusion; ultrafast spectroscopy

Funding

  1. National Science Foundation [NSF-CHE-1555005]
  2. Division of Chemical Sciences, Geosciences and Biosciences of the US Department of Energy
  3. Office of Basic Energy Sciences of the US Department of Energy [DE-AC36-08GO28308]
  4. Division Of Chemistry
  5. Direct For Mathematical & Physical Scien [1555005] Funding Source: National Science Foundation

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By direct imaging of singlet and triplet populations with ultrafast microscopy, it is shown that the triplet diffusion length and singlet fission yield can be simultaneously optimized for tetracene and its derivatives, making them ideal structures for application in bilayer solar cells.

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