4.8 Article

Correlation between Chemical Dopants and Topological Defects in Catalytically Active Nanoporous Graphene

Journal

ADVANCED MATERIALS
Volume 28, Issue 48, Pages 10644-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201604318

Keywords

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Funding

  1. JST-PRESTO Creation of Innovative Core Technology for Manufacture and Use of Energy Carriers from Renewable Energy
  2. JSPS KAKENHI Grant [JP15H05473, JP15K13796, JP25249108, JP20226015, JP26289294]
  3. fusion research funds of World Premier International (WPI) Research Center Initiative for Atoms, Molecules and Materials, MEXT, Japan
  4. NEDO Project Super hybrid material technology development
  5. SIP Project Innovative design/manufacturing technologies on-demand 3D additive manufacturing of structural functional materials and 3D devices through the creation of fluidic material
  6. JST-CREST Phase Interface Science for Highly Efficient Energy Utilization
  7. Kato Foundation for Promotion of Science
  8. Grants-in-Aid for Scientific Research [26289294, 15H05473] Funding Source: KAKEN

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The interplay between chemical dopants and topological defects plays a crucial role in electrocatalysis of doped graphene. By systematically tuning the curvatures, thereby the density of topological defects, of 3D nanoporous graphene, the intrinsic correlation of topological defects with chemical doping contents and dopant configurations is revealed, shining lights into the structural and chemical origins of HER activities of graphene.

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