4.8 Article

Robust Hierarchically Structured Biphasic Ambipolar Oxide Photoelectrodes for Light-Driven Chemical Regulation and Switchable Logic Applications

Journal

ADVANCED MATERIALS
Volume 28, Issue 42, Pages 9308-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201602265

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Funding

  1. EOS Holdings
  2. Swiss Commission for Technology and Innovation via the Swiss Competence Centers for Energy Research (SCCER Heat and Electricity Storage) [KTI.2014.0113]

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Tunable ambipolar photoelectrochemical behavior emerges from microdomains of nanostructured p-type CuFeO2 and n-type Fe2O3 that arise from a single facile solution-processed thin fi lm. The switchable operation of this system is controlled by chemical, optical, or electronic inputs with a uniquely high photocurrent response (on the order of 1 mA cm(-2)), suitable for robust practical application as an oxygen photoregulator.

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