4.8 Article

Edge Functionalization of Graphene and Two-Dimensional Covalent Organic Polymers for Energy Conversion and Storage

Journal

ADVANCED MATERIALS
Volume 28, Issue 29, Pages 6253-6261

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201505788

Keywords

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Funding

  1. National Hi-tech R&D Program of China (863 Program) [2012AA101809]
  2. NSF of China [51502012]
  3. Beijing Natural Science Foundation [2162032]
  4. Start-Up Fund for Talent Introduction of Beijing University of Chemical Technology [buctrc201420]
  5. Talent cultivation of the State Key Laboratory of Organic-Inorganic Composites
  6. Fundamental Research Funds for the Central Universities [ZY1508]
  7. 111 Project [B14004]
  8. NSF
  9. AFOSR-DoD-MURI
  10. DAGSI
  11. Directorate For Engineering
  12. Div Of Civil, Mechanical, & Manufact Inn [1266319] Funding Source: National Science Foundation
  13. Div Of Civil, Mechanical, & Manufact Inn
  14. Directorate For Engineering [1363123] Funding Source: National Science Foundation

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Edge functionalization by selectively attaching chemical moieties at the edge of graphene sheets with minimal damage of the carbon basal plane can impart solubility, film-forming capability, and electrocatalytic activity, while largely retaining the physicochemical properties of the pristine graphene. The resultant edge-functionalized graphene materials (EFGs) are attractive for various potential applications. Here, a focused, concise review on the synthesis of EFGs is presented, along with their 2D covalent organic polymer (2D COP) analogues, as energy materials. The versatility of edge-functionalization is revealed for producing tailor-made graphene and COP materials for efficient energy conversion and storage.

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