4.8 Article

Modulate Organic-Metal Oxide Heterojunction via [1,6] Azafulleroid for Highly Efficient Organic Solar Cells

Journal

ADVANCED MATERIALS
Volume 28, Issue 33, Pages 7269-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201601161

Keywords

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Funding

  1. National 1000 Young Talents Program by China government
  2. 100 Talents Program by Zhejiang University
  3. Asian Office of Aerospace RD [FA2386-15-1-4106]
  4. Office of Naval Research [N00014-1-0170]
  5. National Natural Science Foundation of China [51473142, 21173200, 21473178]
  6. China Scholarship Council [CSC N 201308510084]
  7. Fundamental Research Funds for the Central Universities [ZYGX2014J046]
  8. National Natural Science Funds of China [21503203]
  9. National Basic Research Program of China [2013CB834605]
  10. Scientific Research Grant of Hefei Science Center of CAS (SRG-HSC) [2015SRG-HSC031]

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By creating an effective pi-orbital hybridization between the fullerene cage and the aromatic anchor (addend), the azafulleroid interfacial modifiers exhibit enhanced electronic coupling to the underneath metal oxides. High power conversion efficiency of 10.3% can be achieved in organic solar cells using open-cage phenyl C-61 butyric acid methyl ester (PCBM)-modified zinc oxide layer.

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