4.8 Article

Increasing Polymer Solar Cell Fill Factor by Trap-Filling with F4-TCNQ at Parts Per Thousand Concentration

Journal

ADVANCED MATERIALS
Volume 28, Issue 30, Pages 6491-+

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201601553

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Funding

  1. NSERC of Canada
  2. Canadian Foundation for Innovation
  3. DuPont
  4. A. P. Sloan Foundation

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Intrinsic traps in organic semiconductors can be eliminated by trap-filling with F4-TCNQ. Photovoltaic tests show that devices with F4-TCNQ at parts per thousand concentration outperform control devices due to an improved fill factor. Further studies confirm the trap-filling pathway and demonstrate the general nature of this finding.

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