Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 27, Issue 2, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201603820
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Funding
- Indo-UK APEX project
- Engineering and Physical Sciences Research Council [EP/M023532/1] Funding Source: researchfish
- EPSRC [EP/M023532/1] Funding Source: UKRI
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A new molecularly engineered nonfullerene acceptor, 2,2'-(5,5'-(9,9-didecyl-9H-fluorene-2,7-diyl) bis(benzo[c][1,2,5] thiadiazole7,4-diyl) bis(methanylylidene)) bis(3-hexyl-1,4-oxothiazolidine-5,2-diylidene)) dimalononitrile (BAF-4CN), with fluorene as the core and arms of dicyanon- hexylrhodanine terminated benzothiadiazole is synthesized and used as an electron acceptor in bulk heterojunction organic solar cells. BAF-4CN shows a stronger and broader absorption with a high molar extinction coefficient of 7.8 x 10(4) m(-1) cm(-1) at the peak position (498 nm). In the thin film, the molecule shows a redshift around 17 nm. The photoluminescence experiments confirm the excellent electron accepting nature of BAF-4CN with a Stern-Volmer coefficient (K-sv) of 1.1 x 10(5) m(-1). From the electrochemical studies, the highest occupied molecular orbital and lowest unoccupied molecular orbital energy levels of BAF-4CN are estimated to be -5.71 and -3.55 eV, respectively, which is in good synchronization with low bandgap polymer donors. Using BAF-4CN as an electron acceptor in a poly[(5,6-difluoro-2,1,3-benzothiadiazol-4,7-diyl)-alt-(3,3'''-di(2-octyldodecyl) 2,2; 5', 2 ''; 5 '', 2'''-quaterthiophen-5,5'''-diyl)] based bulk-heterojunction solar cell, a maximum power conversion efficiency of 8.4% with short-circuit current values of 15.52 mA cm(-2), a fill factor of 70.7%, and external quantum efficiency of about 84% covering a broad range of wavelength is achieved.
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