Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 27, Issue 4, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201604328
Keywords
CoP; g-C3N4; dual molecular mechanism; photocatalytic H-2 evolution; surface bonding state
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Funding
- Nanyang Technological University
- Singapore National Research Foundation (NRF) through Cambridge Centre for Carbon Reduction in Chemical Technology (C4T)
- Natural Science Foundation of China [21606114]
- China Scholarship Council (CSC)
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Developing high-efficiency and low-cost photocatalysts by avoiding expensive noble metals, yet remarkably improving H-2 evolution performance, is a great challenge. Noble-metal-free catalysts containing Co(Fe)NC moieties have been widely reported in recent years for electrochemical oxygen reduction reaction and have also gained noticeable interest for organic transformation. However, to date, no prior studies are available in the literature about the activity of N-coordinated metal centers for photocatalytic H-2 evolution. Herein, a new photocatalyst containing g-C3N4 decorated with CoP nanodots constructed from low-cost precursors is reported. It is for the first time revealed that the unique P((-))Co((+))N((-)) surface bonding states lead to much superior H-2 evolution activity (96.2 mu mol h(-1)) compared to noble metal (Pt)-decorated g-C3N4 photocatalyst (32.3 mu mol h(-1)). The quantum efficiency of 12.4% at 420 nm is also much higher than the record values (approximate to 2%) of other transition metal cocatalysts-loaded g-C3N4. It is believed that this work marks an important step toward developing high-performance and low-cost photocatalytic materials for H-2 evolution.
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