Journal
CHEM
Volume 4, Issue 10, Pages 2274-2277Publisher
CELL PRESS
DOI: 10.1016/j.chempr.2018.09.014
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Recent work published by Rovis, Schoenebeck, and co-workers in Nature Chemistry describes a synergistic CO2 mediation and photocatalysis strategy for challenging alpha-alkylation of primary aliphatic amines by using quinuclidine as a hydrogen atom transfer (HAT) catalyst for gamma-lactam synthesis. Electrostatic attraction between the in-situ-generated carbamate and quinuclidinium radical cation is critical for the selectivity.
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