Journal
CHEMISTRYSELECT
Volume 3, Issue 39, Pages 10932-10937Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.201802519
Keywords
Crystal structure; N-Heterocyclic carbenes; Palladium complex; Sonogashira reactions; Triphenylphosphine
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Funding
- Dokuz Eylul University for the use of the Rigaku Oxford Xcalibur Eos Diffractometer (purchased under University) [2010.KB.FEN.13]
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This study contains the synthesis of the novel series of the 2- hydroxyethyl substituted Pd-based N-heterocyclic carbene (NHC) / triphenylphosphine (PPh3) complexes. The (NHC)Pd(II)PPh3 complexes have been prepared from the PPh3 ligand, replaced by 3-chloro pyridine ligand in (NHC)Pd(II)(3-Cl-pyridine) complexes. The novel 2-hydroxyethyl substituted (NHC)Pd(II)PPh3 complexes have been characterized by using (HNMR)-H-1, C-13 {H-1}NMR, P-31 {H-1}NMR, FTIR spectroscopy, and elemental analysis techniques. Molecular and crystal structure of 1f was obtained by using single-crystal X-ray diffraction method. The novel 2-hydroxyethyl substituted (NHC)Pd(II)PPh3 complexes have been examined as catalysts in the Sonogashira cross-coupling reactions aqueous medium and demonstrated excellent activity in this reaction.
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