Laser-Cut Polymer Tape Templates for Scalable Filtration Fabrication of User-Designed and Carbon-Nanomaterial-Based Electrochemical Sensors

We report here a simple filtration method for the scalable fabrication of user-designed and carbon-nanomaterial-based electrode arrays using laser-cut poly(vinyl chloride) (PVC) tape templates. This method can produce electrode arrays with high uniformity and low resistance from the dilute dispersions of single-walled carbon nanotubes (SWNTs) and graphene nanoplatelets (GNPs). For these two carbon arrays, the SWNT array is demonstrated to possess several interesting properties, e.g., good mechanical proper-ties, excellent flexibility, and favorable electrochemical behavior. Moreover, its porous structure enables the construction of a paperlike solid-state electrochemical sensor using Nafion electrolytes, which is suitable for the on-site monitoring of trace phenol pollutants in electrolyte-free water. Besides, an electrochemically addressable 36-zone sensor was constructed by this method. With the aid of an inexpensive 3D printer, the addressable sensor can achieve the semiautomatic and high-throughput evaluation of antioxidant capacity on a series of vegetables and fruits using a single-channel electrochemical analyzer.