4.6 Article

Formation of Magnesium Dendrites during Electrodeposition

Journal

ACS ENERGY LETTERS
Volume 4, Issue 2, Pages 375-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsenergylett.8b02470

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Funding

  1. NSF [DMR 1809866, 1805656]
  2. Div Of Chem, Bioeng, Env, & Transp Sys
  3. Directorate For Engineering [1805656] Funding Source: National Science Foundation

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We demonstrate the growth of dendritic magnesium deposits with fractal morphologies exhibiting shear moduli in excess of values for polymeric separators upon the galvanostatic electrodeposition of metallic Mg from Grignard reagents in symmetric Mg-Mg cells. Dendritic growth is understood on the basis of the competing influences of reaction rate, electrolyte transport rate, and self-diffusion barrier.

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