Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 26, Issue 46, Pages 8545-8554Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.201602736
Keywords
-
Categories
Funding
- Research Grants Council of Hong Kong
- Innovation and Technology Fund of Hong Kong [T23-407/13-N, HKUST 606511, 605710, PolyU 252001/14E, ITS/004/14, ITS/096/14]
- National Natural Foundation of China [61674070, 11574119]
- CUHK Group Research Scheme
Ask authors/readers for more resources
Trap states in semiconductors usually degrade charge separation and collection in photovoltaics due to trap-mediated nonradiative recombination. Here, it is found that perovskite can be heavily doped in low concentration with non-ignorable broadband infrared absorption in thick films and their trap states accumulate electrons through infrared excitation and hot carrier cooling. A hybrid one-sided abrupt perovskite/TiO2 p-N heterojunction is demonstrated that enables partial collection of these trap-filled charges through a tunneling process instead of detrimental recombination. The tunneling is from broadband trap states in the wide depleted p-type perovskite, across the barrier of the narrow depleted TiO2 region (<5 nm), to the N-type TiO2 electrode. The trap states inject carriers into TiO2 through tunneling and produce aroundunity peak external quantum efficiency, giving rise to near-infrared photovoltaics. The near-infrared response allows photodetecting devices to work in both diode and conductor modes. This work opens a new avenue to explore the near-infrared application of hybrid perovskites.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available