4.6 Article

Titanium Phosphate Nanoplates Modified With AgBr@Ag Nanoparticles: A Novel Heterostructured Photocatalyst With Significantly Enhanced Visible Light Responsive Activity

Journal

FRONTIERS IN CHEMISTRY
Volume 6, Issue -, Pages -

Publisher

FRONTIERS MEDIA SA
DOI: 10.3389/fchem.2018.00489

Keywords

heterojunction; titanium phosphate; AgBr@Ag; photocatalysis; visible light

Funding

  1. National Science Funds for Creative Research Groups of China [51421006]
  2. Natural Science Foundation of China [51679063]
  3. Fundamental Research Funds for The Central Universities [2018B14514]
  4. National Natural Science Foundation of China [91647206]
  5. National Key Plan for Research and Development of China [2016YFC0502203]
  6. PAPD

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AgBr@Ag modified titanium phosphate composites were fabricated through a two-step approach. The prepared samples were characterized by X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. The optical properties of the composites were characterized by using UV-vis diffuse reflectance spectroscopy. The photocatalytic activities of the composites were investigated on the degradation of Rhodamine B and ciprofloxacin under visible light irradiation. AgBr@Ag/titanium phosphate was determined to exhibit considerably higher photocatalytic activity than the corresponding individual components. The mechanism on the enhancement of the photocatalytic activity was proposed based on the results of photoluminescence spectra and photocurrent measurements. Furthermore, the possible photocatalytic mechanisms of organic compounds degradation were also proposed.

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