Journal
CATALYSTS
Volume 9, Issue 1, Pages -Publisher
MDPI
DOI: 10.3390/catal9010053
Keywords
Suzuki cross-coupling; acyl cross-coupling; acylation; ketones; acylative cross-coupling; palladium; nickel; phosphine; N-heterocyclic carbene; Suzuki-Miyaura
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Funding
- Rutgers University
- NSF [CAREER CHE-1650766]
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Acyl Suzuki cross-coupling involves the coupling of an organoboron reagent with an acyl electrophile (acyl halide, anhydride, ester, amide). This review provides a timely overview of the very important advances that have recently taken place in the acylative Suzuki cross-coupling. Particular emphasis is directed toward the type of acyl electrophiles, catalyst systems and new cross-coupling partners. This review will be of value to synthetic chemists involved in this rapidly developing field of Suzuki cross-coupling as well as those interested in using acylative Suzuki cross-coupling for the synthesis of ketones as a catalytic alternative to stoichiometric nucleophilic additions or Friedel-Crafts reactions.
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