A Review on Ultrasonic Catalytic Microbubbles Ozonation Processes: Properties, Hydroxyl Radicals Generation Pathway and Potential in Application

Ozone-based advanced oxidant processes (AOPs) have attracted remarkable attention as an alternative and effective approach for mineralization of refractory organics to innocuous substances. Key issues for ozone-based AOPs mainly focused on how to enhance ozone mass transfer and improve the production of hydroxyl radicals. Unfortunately, great efforts have been made, though, the application of ozone-based AOPs still remained in the laboratory scale due to lack of understanding of mechanisms of these hybrid processes. Besides, obtaining the balance of economical-technical feasibility is a great challenge. Ultrasonic catalytic microbubbles ozonation could be considered as a promising method, despite that there are a few studies that addressed this potential technology. Therefore, in this review, summaries about ozone-based microbubbles process, ultrasonic catalytic ozonation process, and ultrasonic catalytic microbubbles ozonation process have been provided in order to give a novel prospective about these hybrid technologies. The main influential parameters, such as initial pH, ozone dosage, intake flow rate, operating temperature, bubble size distributions, ultrasonic frequency, ultrasonic power density, and natural water constituents have also been well discussed. We truly hope that this paper will bring convenience to researchers that are devoted in the field of application of ozone-based AOPs for mineralizing refractory organics in wastewater.