Journal
ADVANCED MATERIALS INTERFACES
Volume 6, Issue 2, Pages -Publisher
WILEY
DOI: 10.1002/admi.201801424
Keywords
cellulose nanofibril; flame resistance; layer-by-layer assembly; mechanical properties; oxygen barrier
Funding
- Sandia National Laboratories [1851508]
- Swedish Foundation for Strategic Research (SSF)
- Wallenberg Wood Science Centre
Ask authors/readers for more resources
Cellulose nanofibrils (CNF) are abundant in the fiber cell walls of many plants and are considered a nearly inexhaustible resource. With the goal of improving the flame resistance and gas barrier properties of cellulose-based films, cationic CNF are assembled with anionic vermiculite (VMT) clay using the layer-by-layer deposition process. The highly aligned VMT nanoplatelets, together with cellulose nanofibrils, form a nanobrick wall structure that exhibits high optical transparency, flame resistance, super oxygen barrier, and high modulus. A 20 CNF/VMT bilayer (BL) nanocoating, with a thickness of only 136 nm, exhibits an oxygen transmission rate of 0.013 cc (m(2) day atm)(-1). With only 2 BL of CNF/VMT, the melting of flexible polyurethane foam exposed to a butane torch is prevented. These nanocoatings also exhibit a high elastic modulus (20 GPa) and hardness (1 GPa). This study demonstrates a unique, renewable, cellulose-based nanocoating that could be used in a variety of packaging and protection applications.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available