Journal
NANO ENERGY
Volume 55, Issue -, Pages 49-58Publisher
ELSEVIER
DOI: 10.1016/j.nanoen.2018.10.017
Keywords
Multi-functional electrocatalysts; Water splitting; Carbon coated metal oxides; All-pH electrolysis; Regenerative fuel cells
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Funding
- National Research Foundation [2016H1A2A1909427, 2017M1A2A2087813]
- Korea Carbon Capture AMP
- Sequestration RD Center [2014M1A8A1049296]
- Ministry of Education (BK21Plus), Republic of Korea [10Z20130011057]
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Partially hydrous RuO2 nanocluster embedded in a carbon matrix (x-RuO2@C with x = hydration degree = 0.27 or 0.27@C) is presented as a bifunctional catalyst for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) for water splitting. Symmetric water electrolyzers based on 0.27-RuO2@C for both electrodes showed smaller potential gaps between HER and OER at pH 0, pH 14 and even pH 7 than conventional asymmetric electrolyzers based on two different catalysts (Pt/C parallel to Ir/C) that have been known as the best catalysts for HER and OER respectively. Moreover, 0.27-RuO2@C showed another bifunctional electroactivity for fuel cell electrochemistry involving hydrogen oxidation reaction (HOR) and oxygen reduction reaction (ORR) that are the backward reactions of HER and OER respectively. Pt-level HOR electroactivity was obtained from 0.27-RuO2@C, while its ORR activity was inferior to that of Pt with 200 mV higher overpotential required. The tetra-functionality of 0.27-RuO2@C showed the possibility of realizing single-catalyst regenerative fuel cells.
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