Journal
ACS CATALYSIS
Volume 8, Issue 12, Pages 11657-11662Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.8b03770
Keywords
bimetallic; nickel; alkylation; C-H activation; reaction mechanism
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Funding
- European Research Council under the European Community [307535]
- Regione Lombardia-Cariplo Foundation
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A set of bimetallic nickel(II)/nickel(II) complexes featuring paddle-wheel structures was synthesized and fully characterized. These homobimetallic nickel complexes were identified as powerful catalysts for challenging aniline CH activations with primary and secondary b-hydrogen-containing alkyl halides.
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