Journal
ACS CATALYSIS
Volume 9, Issue 1, Pages 599-604Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.8b04713
Keywords
ring-closure; C-H activation; dienes; hydroarylation; rare earths
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Funding
- National Natural Science Foundation of China [21371131]
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A highly regio- and diastereoselective, cyclization/hydroarylation reaction of 1,5- and 1,6-dienes with aromatic ethers and tertiary anilines was established by a cationic 2-picoline-tethered-half-sandwich scandium alkyl catalyst, which constitutes a process for producing a diverse array of cis-1,3-disubstituted arylated and trans-1,2-disubstituted benzylated methylcyclopentane derivatives in one step with 100% atom-efficiency. Furthermore, a mechanism involving a scandium-catalyzed aromatic ortho-C-H activation and alkene-insertion cascade was also proposed.
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