Journal
WATER ENVIRONMENT RESEARCH
Volume 90, Issue 11, Pages 1925-1937Publisher
WATER ENVIRONMENT FEDERATION
DOI: 10.2175/106143017X15131012188132
Keywords
adsorbent; carbon nanospheres; heavy metals; hexavalent chromium; wastewater treatment
Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC - Canada)
- Canada Foundation for Innovation (CFI - Canada)
- Algerian Ministry of Higher Education
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Carbon nanospheres were prepared and functionalized with carboxyl acid groups (CNS-CA), then reacted with 3-aminopropyltriethoxysilane to introduce amino groups onto the surface (CNS-NH2) by post-synthesis grafting. CNS-NH2 was acidified in order to convert the amino groups (-NH2) into ammonium moieties (-NH3+). Various techniques such as N-2 physisorption, X-ray diffraction, Fourier transform infrared spectroscopy, Raman spectroscopy, thermogravimetry, X-ray photoelectron spectroscopy, and transmission electron microscopy were used to characterize the nanospheres. The removal of chromium ions from aqueous solution using CNS-NH3+ was investigated. Factors influencing the uptake of Cr(VI) ions such as solution pH, adsorbent dose, and initial Cr(VI) ion concentration were investigated. Equilibrium adsorption data fitted the Langmuir model very well. The adsorption maximum capacity of Cr(VI) was found to be 52.38 mg/g. The reusability of CNS-NH3+ results indicated that it can be reused five times successfully without loss of adsorption capacity.
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