Journal
TETRAHEDRON
Volume 75, Issue 2, Pages 193-208Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2018.11.026
Keywords
Total synthesis; Cyclopropanol; Natural product; Ring opening; Metal catalysis
Categories
Funding
- NSF [CAREER 1553820]
- Eli Lilly
- Amgen
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Cyclopropanols are readily available via the Kulinkovich cyclopropanation, the Simmons-Smith reaction, and other synthetic methods. Due to their intrinsic ring stains, cyclopropanols and their derivatives are highly reactive and can be converted to different structural scaffolds which are frequently found in many natural products. In this review, we highlight the applications of various cyclopropanol ring opening/expansion/fragmentation reactions in the total syntheses of natural products. (C) 2018 Elsevier Ltd. All rights reserved.
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