Journal
TETRAHEDRON
Volume 74, Issue 51, Pages 7290-7301Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2018.10.061
Keywords
Allene; Heteroatom radical; Carbon radical; Regioselectivity; Stereoselectivity
Categories
Funding
- National Natural Science Foundation of China [21502069, 21772067]
- China Postdoctoral Science Foundation [2018M630396]
Ask authors/readers for more resources
This review is focused on the recent advances in the functionalization of allenes via radical process. Different radical partners including carbon radicals and heteroatom radicals are discussed in the reactions of allenes. Generally, the radical formed in situ would attack the allene at the central carbon leading to allyl radical intermediate. However, the formation of alkenyl radical intermediate from allene could be observed as well in some cases with high regioselectivity and stereoselectivity. (C) 2018 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available