Journal
SYNTHETIC COMMUNICATIONS
Volume 48, Issue 23, Pages 3025-3032Publisher
TAYLOR & FRANCIS INC
DOI: 10.1080/00397911.2018.1532519
Keywords
Homogeneous catalysis; organosilicon chemistry; ruthenium hydride complex; silatranes; silylative coupling
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Funding
- National Science Centre (Narodowe Centrum Nauki, Poland) [2011/02A/ST5/00472]
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Protocols for the synthesis of cage-substituted 1-vinylsilatranes have been developed and updated. The 1-vinylsilatranes with organic substituents attached to silatrane cage were functionalized in ruthenium-catalyzed trans-silylation with olefins, leading to novel styrylsilatranes in high yields.
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