Journal
SYNTHESIS-STUTTGART
Volume 51, Issue 3, Pages 629-642Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1610321
Keywords
adamantane; diamondoid; C-H functionalization; C-H activation; insertion reactions; hydrogen abstraction reactions; hydride shift
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Funding
- DFG [HR 97/1-1]
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This review summarizes the synthetic approaches towards 1,2-substitution pattern on the adamantane framework. Selected are the works containing the directed C-H functionalization step. 1 Introduction 2 Access to 1,2-Disubstituted Derivatives via C-H Insertion Reactions of Electrophilic Organic Species 3 Access to 1,2-Disubstituted Derivatives through Hydrogen Radical Abstraction Reactions 4 Access to 1,2-Disubstituted Derivatives Exploiting Metal-Catalyzed (Promoted) C-H Activations 5 Access to 1,2-Disubstituted Derivatives via Hydride Shift 6 Conclusion 7 Acronyms
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