Journal
SYNTHESIS-STUTTGART
Volume 51, Issue 5, Pages 1216-1224Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1611653
Keywords
enynes; palladium; platinum; clusters; aromaticity; cyclization
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Funding
- Ministero dell'Istruzione, dell'Universita e della Ricerca (MIUR
- grant AROMA-TriP)
- Ministero dell'Istruzione, dell'Universita e della Ricerca (Departments of Excellence framework)
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The distinct reactivity of 1,6-enynes in the presence of a trinuclear metal complex activated by a carboxylic acid is presented. The triplatinum catalyst enables the cyclization of the substrate and subsequent incorporation of a nucleophile in the final product. In contrast, sequential cyclization/double bond shift occurs under analogous conditions in the presence of the corresponding tripalladium complex.
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