Journal
SYNTHESIS-STUTTGART
Volume 51, Issue 14, Pages 2865-2870Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1610322
Keywords
visible light; trifluoromethylthiolation; arenediazonium; radical; reaction mechanism
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Funding
- la region Auvergne Rhone Alpes
- CNRS
- ICL (Institut de Chimie de Lyon)
- French Fluorine Network
- federation RENARD
- ICBMS (UMR 5246)
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The visible-light-mediated synthesis of trifluoromethylthiolated arenes in the presence of ruthenium-based photocatayst under mild reaction conditions is reported. The trifluoromethylthiolated arenes are obtained using the shelf-stable reagent trifluoromethyl toluenethiosulfonate at room temperature. The reaction proceeds selectively and does not require the presence of any additive. A mechanism is proposed based on the obtained results of EPR as well as luminescence
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