Journal
SYNLETT
Volume 30, Issue 10, Pages 1174-1177Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1611942
Keywords
C-C coupling; protecting groups; electrochemistry; C-H activation; arylation; terphenyls
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Funding
- DFG [Wa1276/14-1]
- Carl-Zeiss Foundation
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The anodic C-C cross-coupling reaction provides fast access to a wide range of bi- and terarylic scaffolds by electrochemically mediated arylation reactions. Herein, a metal- and reagent-free electrosynthetic protocol for the synthesis of nonsymmetrical 2-hydroxy- para -teraryl derivatives is presented for the first time. It is scalable, easy to conduct, and allows the use of a broad variety of different functional groups.
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