Journal
SUPERLATTICES AND MICROSTRUCTURES
Volume 125, Issue -, Pages 287-294Publisher
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.spmi.2018.11.018
Keywords
Cu2ZnSn(S,Se)(4); Ag doping; Solar cell; Selenization temperature; Power conversion efficiency
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Funding
- National Natural Science Foundation of China [61774075, 11274135, 61604029, 61505067]
- Science and Technology Development Project of Jilin Province [20170101142JC]
- Specialized Research Fund for the Doctoral Program of Higher Education [20130061130011]
- Ph.D. Programs Foundation of Ministry of Education of China [20120061120011]
- Graduate Innovation Fund of Jilin University [2017051]
- High Performance Computing Center of Jilin University, China
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(Cu1-xAgx)(2)ZnSn(S,Se)(4) films with Ag content of x = 0 (CZTSSe), 0.05 (CAZTSSe) and the corresponding solar cells were fabricated on soda-lime glass (SLG) substrates by sol-gel method and rapid selenization thermal processing (RTP). As Ag is alloyed into CZTSSe, Cu+ cation in CZTSSe films was replaced by Ag+ cation, leading to the improvement in crystal quality, the decrease of hole concentration and the increase of bandgap. We observed an increase in open-circuit voltage (V-OC) and an accompanying rise in device efficiency from 4.48% to 5.94% as Ag is alloyed into CZTSSe. To further improve the efficiency, we optimized the selenization temperature of the CAZTSSe films. It is found that the optimized selenization temperature is 530 degrees C and the best efficiency of the corresponding CAZTSSe solar cell is 7.91%. The improvement of device performance with selenization temperature is mainly attributed to the optimization of device parameters such as reversion saturation current density (J(0)), diode ideal factor (A) and series resistance (R-s), which are determined by crystal quality and grain size of CAZTSSe films as well as structure of the CAZTSSe/CdS and CAZTSSe/Mo interfaces.
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