Journal
STRUCTURAL CHEMISTRY
Volume 30, Issue 2, Pages 451-456Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11224-018-1260-8
Keywords
Ionic liquids; Thermal analysis; Crystal structure; NMR spectroscopy; Electrochemical window; Conductivity
Funding
- Russian Science Foundation [18-13-00217]
Ask authors/readers for more resources
Dicationic ionic liquid (IL) dibutyltetramethylethylenediammonium tetrafluoridoborate was synthesized for the first time by quaternization followed by ion exchange. The chemical composition was confirmed by H-1, F-19, and C-13 nuclear magnetic resonance (NMR) spectroscopy. The crystal structure of the IL under discussion was determined from single crystal diffraction and can be described in monoclinic syngony with P2(1)/c space group. Using thermal analysis and mass spectrometry, thermal stability of this IL as well as possible directions of its destruction was analyzed. Melting point for this liquid was determined by simultaneous thermal analysis as 135 degrees C. The electrochemical stability range for this ionic liquid was find to be nearly symmetrical accordingly to cyclic voltammetry and estimated as 3.75V.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
