Journal
SMALL
Volume 15, Issue 29, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.201803513
Keywords
bond angle; covalency; oxygen reduction reaction; perovskites
Categories
Funding
- National Natural Science Foundation of China [21801089, 21671076, 21427802, 21131002]
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Identifying the relationship between catalytic performance and material structure is crucial to establish the design principle for highly active catalysts. Deficiency in B-O bond covalency induced by lattice distortion severely restricts the oxygen reduction reaction (ORR) performance for ABO(3)-type perovskite oxides. Herein, a rearrangement of hybridization mode for B-O bond is used to tune the overlap of the electron cloud between B 3d and O 2p through A-stie doping with larger radius ions. The B-O bond covalency is strengthened with a B-O-B bond angle recovered from intrinsic structural distortion. As a result, the adsorption and the reduction process for O-2 on the oxide surface can be promoted via shifting the O-2p band center toward the Fermi Level. Simultaneously, the spin electrons in the Mn 3d orbit become more parallel. It will lead to a high electrical conductivity by the enhanced double exchange process and thereof mitigate the ORR efficiency loss. Further density functional theory calculation reveals that a flat [BO2] plane will make contribution to the charge transfer process from lattice oxygen to adsorbed oxygen (mediated with B ions). Through such exploration of the effect of crystal structure on the electronic state of perovskite oxides, a novel insight into design of highly active ORR catalysts is offered.
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